If installed on any site collection other than the root site, it will be seen as an additional tab in the Teams channel.
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Go to the tenant admin apps page from the below URL format and click on classic experience options.
https://yourtenantname.sharepoint.com/sites/appcatalog/_layouts/15/tenantAppCatalog.aspx/manageApps
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Click on Apps for SharePoint as shown below.
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Select the Employee Directory application and click on Files and then Sync to Teams.
These displays Sync to Teams successfully.
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Navigate to Teams and click on Add a tab
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Search and select the Employee Directory application. Then click on add.
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Next, click on Save and you can see Employee Directory application in teams.